Comparison of the 13C (C = N) chemical shifts of substituted N‐(phenyl‐ethylene)‐anilines and substituted N‐(benzylidene)‐anilines

Comparison of ¹³C NMR of C = N bond chemical shifts δ_C(C = N) in substituted N‐(phenyl‐ethylene)‐anilines XArC(Me) = NArY (XPEAYs) with that in substituted N‐(benzylidene)‐anilines XArCH = NArY (XBAYs) was carried out. The δ_C(C = N) of 61 samples of XPEAYs were measured, and the substituent effect on their δ_C(C = N) were investigated. The results show the factors affecting the δ_C(C = N) of XPEAYs are quite different from that of XBAYs. A penta‐parameter correlation equation was obtained for the 61 compounds, which has correlation coefficient 0.9922 and standard error 0.12 ppm. The result indicates that, in XPEAYs, the inductive effects of substituents X and Y are major factors affecting the δ_C(C = N), while the conjugative effect of them have very little effect on the δ_C(C = N) and can be ignored. The substituent‐specific cross‐interaction effects between X and Y and between Me of C = N bond and substituent Y are important factors affecting the δ_C(C = N). Also, the excited‐state substituent parameter of substitute Y has certain contribution to the δ_C(C = N). Copyright © 2015 John Wiley & Sons, Ltd.     

锌磷酸盐玻璃掺杂VO~(2+)吸收光谱和EPR谱研究

3d1离子(如VO2+,V4+)是一类非常重要的离子,其掺杂电子顺磁共振谱已有大量的研究,积累了丰富的实验数据。利用3d1离子在四角压缩八面体对称中EPR参量的高阶微扰公式,计算了锌磷酸盐玻璃晶体中掺杂VO2+的EPR参量(g因子g‖,g⊥和超精细结构常数A‖,A⊥)和光吸收谱。由于锌磷酸盐玻璃晶体中掺杂VO2+中配体O2-的自旋-轨道耦合参量ζ0p(≈150cm-1)与中心过渡金属3d1离子V4+的ζ0d(≈248cm-1)相差不太大,故来自配体的自旋-轨道耦合参量ζ0p对EPR参量和光吸收谱的贡献必须予以考虑。采用重叠模型建立了杂质中心结构参数与电子顺磁共振(EPR)参量以及光吸收谱之间的定量关系;通过拟合锌磷酸盐玻璃中V4+中心的EPR参量和光吸收谱理论与试验符合,获得了杂质中心[VO6]8-基团的局域结构;研究发现,[VO6]8-基团的平行和垂直于C4轴的键长分别为:R‖≈0.175nm,R⊥≈0.197nm,即[VO6]8-基团的局域结构为沿C4轴方向呈压缩的八面体结构;所得EPR参量和光吸收谱的理论值与实验符合很好,并对上述结果的合理性进行了讨论。这说明微扰法可以用来研究材料中掺杂3d1过渡金属离子的EPR参量和光吸收谱。此外,对超精细结构常数(A‖和A⊥)的研究发现,较大的芯区极化常数κ值说明VO2+中未配对的s电子对超精细结构常数有较大的贡献。     

三山岛金矿控矿断层F1的力学性质及补强措施

作者以正在开采中的三山岛金矿采场为研究对象，分析矿区开采过程中的岩体结构特征及重力方向矿柱、护顶矿柱与控矿断层F1断层泥及其上覆岩体之间的关系和力学机制。通过试验研究了断层泥的物质成分和力学性质，总结了力学特性与断层泥厚度及含水量之间的关系。在此基础上提出锚固大于中倾角的结构面，提高结构面的抗滑阻力；增加含有高、陡倾角结构面矿柱的刚度等对矿柱的补强措施。对护顶矿柱提出预先锚固；分阶段开采的补强方法。在裂隙密集带设置排水设施，改善断层泥的赋存条件，提高它的力学性能。     

涡流检波器特性测量与参数识别

新型涡流检波器已在地质、石油、煤炭人工地震勘探中采用。本文将最新的振动试验方法、数据处理技术及模态参数识别应用到检波器特性参数的确定中。论述它的有效优化方法,并首次将它应用到传感器的标定技术中,做到快速准确测定它的参数值,为检波器的生产、使用提供技术保证,亦为涡流检波器参数综合测试仪研制提供理论基础。     

基于神经网络的误差补偿滤波器在陀螺漂移误差模型辨识中的应用

用神经网络补偿非线性卡尔曼滤波器的状态估计误差，并将其用于陀螺漂移误差模型的参数辨识中，仿真结果表明该方法的有效性。     

GPS误差模型参数估计的Hopfield神经网络方法

本文首先建立了ＧＰＳ误差模型。然后，利用Ｈｏｐｆｉｅｌｄ神经网络（ＨＮＮ）方法对误差模型参数进行了估计，并给出了其硬件实现方法。将估计结果与传统的最小二乘（ＬＳ）估计进行比较，证明了神经网络方法的有效性。     

Poincaré Mapping Method for Hydrodynamic Systms. Dynamic Chaos in a Fluid Layer between Eccentrically Rotating Cylinders

Investigation of the plane–parallel motion of particles of an incompressible medium reduces to investigation of a Hamiltonian system. The Hamiltonian function is a stream function. The timeperiodic mixing of an incompressible medium is described by a timeperiodic Hamiltonian function. The mixing of the medium is associated with dynamic chaos. Transition to dynamic chaos is studied by analysis of the positions of Lagrangian particles at times divisible by the period — Poincaré recurrence points. The set of Poincaré recurrence points is studied with the use of Poincaré mapping on the phase flow. A method for constructing Poincaré maps in parametric form is proposed. A map is constructed as a series in a small parameter. It is shown that the parametric method has a number of advantages over the generating function method is shown. The proposed method is used to examine the motion of particles of an incompressible viscous fluid layer between two circular cylinders. The outer cylinder is immovable, and the inner cylinder rotates about a point that does not coincide with the centers of both cylinders. An optimal mode for the motion is established, in which the area of the chaotic region is maximal.     

多传感器融合技术在低成本车辆组合导航定位系统中的应用

采用多传感器信息融合技术，运用位置/航向的输出校正和元件参数误差的补偿校正的方法，利用一阶马尔可夫模型建立了传感器参数的误差模型，提出了基于集中卡尔曼滤波的GPS/INU车辆组合导航算法。仿真结果表明上述方法是行之有效的。     

碰撞角对爆炸复合材料界面状态的影响

复合材料界面状态是衡量复合质量优劣的主要评定因素之一,焊接参数和界面状态之间存在着紧密的联系。为了获得理想的复合质量,必须正确选择爆炸焊接参数。本文在实验的基础上,通过理论研究和数值计算,探讨了爆炸复合的力学模型及物理机制,验证了碰撞角对再入射流的质量(或再入射流的厚度)和爆炸复合材料界面状态存在的影响,得出了波形的变化趋势与碰撞角的变化趋势相一致的结论,同时确立了波形参数和碰撞角的半定量表达式,拓展和深化了爆炸复合的研究领域,丰富和发展了爆炸复合的成波机理,从而能够更好地指导工程应用,减少工程损耗,提高复合质量和工作效率。